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Chemistry · Pi Bond

Why is a pi (π) bond inherently weaker than a sigma (σ) bond?

Verified Solution4 OptionsUpdated: October 2026

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1The shared electrons are held tightly between the two nuclei.
2The extent of orbital overlapping is significantly lesser.✓
3It results from the overlapping of s-orbitals.
4It is formed along the internuclear axis.

Correct answer

The extent of orbital overlapping is significantly lesser.

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Why is a pi (π) bond inherently weaker than a sigma (σ) bond?

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