Chemistry · Pericyclic Reactions
Under thermal conditions, which of the following statements is correct regarding the stereochemical outcome of [1, 5]-sigmatropic shifts of carbon and hydrogen?
- 1[1, 5]-carbon shift with inversion and [1, 5]-hydrogen shift with retention
- 2both [1, 5]-carbon shift and [1, 5]-hydrogen shift with retention
- 3[1, 5]-carbon shift with retention and [1, 5]-hydrogen shift with inversion
- 4both [1, 5]-carbon shift and [1, 5]-hydrogen shift with retention✓
Correct answer
both [1, 5]-carbon shift and [1, 5]-hydrogen shift with retention
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