Chemistry · Molecular Spectroscopy
The following data is obtained for a light diatomic (AB) molecule from its rotational-vibrational Raman spectrum: Be = 2 cm-1, xe = 0.01, and νe = 1600 cm-1. If the molecule is irradiated by a laser of 20,000 cm-1, the expected Stokes lines for the fundamental vibrational transition (v=0 to v=1, with ΔJ = -2, 0, +2) are given in cm-1 by which series?
- 118416, 18424, 18430, 18440, 18452
- 218380, 18388, 18400, 18412, 18420
- 318412, 18420, 18432, 18444, 18452✓
- 418348, 18356, 18368, 18380, 18388
Correct answer
18412, 18420, 18432, 18444, 18452
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