Chemistry · Electrochemistry
Standard electrode potentials (E°) for some half-cell reactions are given below: (a) H+(aq) + e− → 12H2(g) ; E° = 0.00 V (b) 2H2O(l) → O2(g) + 4H+(aq) + 4e− ; E° = 1.23 V (c) 2SO42−(aq) → S2O82−(aq) + 2e− ; E° = 1.96 V On the basis of these, which of the following statements is correct?
- 1In dilute sulphuric acid solution, hydrogen gas will be evolved at the anode.
- 2In dilute sulphuric acid solution, water will be preferentially oxidised at the anode.✓
- 3In dilute sulphuric acid solution, SO42− ion will be oxidised to peroxodisulphate ion at the anode.
- 4In concentrated sulphuric acid solution, water will be preferentially oxidised at the anode.
Correct answer
In dilute sulphuric acid solution, water will be preferentially oxidised at the anode.
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