Chemistry · Organometallic Chemistry
Match the description of metal-alkyl compounds that do not undergo β-hydride elimination (List I) with the correct reasons (List II): List I A. Ti(CH2Ph)4 B. [Ti(Me)4(dmpe)] C. Cr(1-adamantyl)4 D. W(Me)6 List II P. Lacks β-hydrogen Q. No vacant coordination site on the metal center R. Leads to a bridgehead olefin S. A planar transition state is not accessible Select the correct match:
- 1A-S, B-P, C-R, D-Q
- 2A-R, B-S, C-P, D-Q
- 3A-Q, B-R, C-S, D-P
- 4A-P, B-Q, C-R, D-P✓
Correct answer
A-P, B-Q, C-R, D-P
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