Chemistry · Coordination Compounds
In the reaction sequence starting with solid thiourea reacting with P in dilute acetic acid to yield N 2 gas, SCN - , and H 2 O, followed by reaction with dilute FeCl 3 to give a blood-red solution Q, which then turns into a colorless solution R upon adding dilute HgCl 2 , the correct species P, Q, and R are respectively:
- 1NaN 3 , N 2 , [Fe(H 2 O) 5 (N 3 )] 2+ , [Hg(N 3 ) 4 ] 2-
- 2KNO 3 , N 2 , [Fe(H 2 O) 5 (CN)] 2+ , [Hg(OCN) 4 ] 2-
- 3KNO 2 , N 2 , [Fe(H 2 O) 5 (SCN)] 2+ , [Hg(SCN) 4 ] 2-✓
- 4KNO 2 , CO 2 , [Fe(H 2 O) 5 S] + , HgS
Correct answer
KNO 2 , N 2 , [Fe(H 2 O) 5 (SCN)] 2+ , [Hg(SCN) 4 ] 2-
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