Chemistry · Inorganic Polymers
In phosphazene chemistry, when hexachlorocyclotriphosphazene, [NPCl2]3, reacts with sodium alkoxide (NaOR) in partial stoichiometric ratios, which statement correctly describes the substitution pathway?
Verified Solution4 OptionsUpdated: October 2026👁️1 View
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- 1NaOR attacks nitrogen first, leading to ring opening
- 2Non-geminal substitution occurs exclusively on alternate nitrogen atoms
- 3Geminal substitution is preferred predominantly at the same phosphorus atom✓
- 4Substitution is completely random and statistical
Correct answer
Geminal substitution is preferred predominantly at the same phosphorus atom
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