Chemistry · Organometallic Chemistry & Transition Metal Nitrosyls
For an iron-nitrosyl complex reaction sequence, the doubly reduced species exhibits an N-O stretching frequency of 1496 cm-1. The correct statement regarding this doubly reduced species is:
Verified Solution4 OptionsUpdated: October 2026👁️1 View
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- 1The reduction is fully localized on the metal.
- 2The reduction is predominantly localized on the NO ligand.✓
- 3There is no back-bonding interaction between iron and NO.
- 4The Fe-NO bond length remains unaffected upon reduction.
Correct answer
The reduction is predominantly localized on the NO ligand.
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