Chemistry · Organic Compounds Containing Nitrogen
Comparing 1,4-dimethyl-3-nitroaniline (Structure A) and 1,5-dimethyl-3-nitroaniline (Structure B), identify the stronger base and the correct reason.
Verified Solution4 OptionsUpdated: October 2026👁️1 View
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- 1B : steric inhibition of resonance due to CH 3 group
- 2A : NO 2 group does not effectively delocalize the electron pair of NH 2✓
- 3A : steric hindrance due to CH 3 group
- 4B : NO 2 group deactivates the ring
Correct answer
A : NO 2 group does not effectively delocalize the electron pair of NH 2
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